Just a short quote from: http://www.marinedepot.com/aquarium_mar ... ?ast=&key=
Protein skimming
By Mike Paleta
It is possible to overskim the tank if too much water is run through the skimmers. Overskimming means taking an excess of good trace elements out of the water, which can be just as deleterious to the inhabitants as allowing an excess of dissolved organics to remain in the water. When a properly designed skimmer is used, if the amount of dissolved organics drops below a certain threshold then the amount of foam will be reduced and no additional skimming will result, therefore it is usually difficult to overskim an aquarium. However, with the newer more efficient skimmers, it is now much easier to overskim a tank since these skimmers are indiscriminate in terms of what they remove.
The possibility of overskimming a tank has led to the debate of whether these skimmers and trace elements should be used at all since all that is really occurring is the removal of the trace elements that were just added. The problem with this argument is that it neglects the need to remove waste and other deleterious materials that accumulate regardless of whether good compounds are removed or not. It is probably best to remove as much material, both good and bad, as efficiently as possible and then add the compounds and elements that have been deemed good or positive. In this way efficient skimming can be used to maintain more positive compounds in the water by allowing what is essential to be added to replace what has been removed. This may also be another reason why it may be necessary to "feed" the corals and other invertebrates in a tank using a powerful skimmer where that was not the case when less efficient skimmers were being used.
Mike Paletta is the author of The New Marine Aquarium and Ultimate Marine Aquariums.